1,3-Di-4-pyridylpropane–4,4′-oxydibenzoic acid (1/1)
نویسندگان
چکیده
The hydro-thermal reaction of Cd(NO(3))(2)·4H(2)O, 1,3-di-4-pyridylpropane (BPP) and 4,4'-oxydibenzoic acid (OBA) led to the formation of the title compound, C(13)H(14)N(2)·C(14)H(10)O(5). The asymmetric unit consists of one mol-ecule of OBA and one of BPP. In the OBA mol-ecule, one COOH group is nearly planar with its attached benzene ring [dihedral angle = 0.9 (1)°], while the other COOH group is slightly twisted with a dihedral angle of 10.8 (3)°. The carboxyl groups form strong inter-molecular O-H⋯N hydrogen bonds with N atoms of the pyridine rings in BPP, linking the mol-ecules into zigzag chains.
منابع مشابه
Poly[di-μ2-chlorido(μ2-1,3-di-4-pyridylpropane-κ2 N:N′)lead(II)]
The title Pb(II) coordination polymer, [PbCl(2)(C(13)H(14)N(2))], was prepared by the hydro-thermal reaction of PbCl(2) with 4,4,-trimethyl-enedipyridine in a 1:1 ratio. It exhibits a two-dimensional layered structural motif consisting of PbCl(2) chains and the flexible bridged 4,4'-trimethyl-enedipyridine ligand. The connections result in a cavity of about 4 × 15 Å.
متن کاملcatena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ2 O 1,O 2)cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ2 N:N′] dihydrate]
In the title compound, {[Co(C(7)H(3)NO(5))(C(13)H(14)N(2))(H(2)O)]·2H(2)O}(n), the Co(II) atom is coordinated by two O atoms from a pyridine-2,6-dicarboxyl-ate N-oxide ligand, two N atoms from two 1,3-di-4-pyridylpropane ligands and one water mol-ecule, and displays a distorted square-pyramidal coordination geometry. The 1,3-di-4-pyridylpropane ligands link the Co(II) atoms into an infinite zig...
متن کاملPoly[μ2-benzene-1,3-dicarboxylato-κ2 O:O′-μ2-1,3-di-4-pyridylpropane-κ2 N:N′-zinc(II)]
The title compound, [Zn(C(8)H(4)O(4))(C(13)H(14)N(2))](n), was obtained by the hydro-thermal reaction of Zn(OAc)(2)·H(2)O with 1,3-di-4-pyridylpropane (bpp) and isophthalic acid (H(2)ip). The Zn(II) ion is coordinated by two bpp and two ip ligands in a distorted tetra-hedral environment. Each ligand coordinates in a bridging mode to connect Zn(II) ions into a three-dimensional diamondoid-type s...
متن کاملcatena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ2 N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)]
In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octa-hedral coordination environment. The 1,3-di-4-pyridylpropane ligands...
متن کاملcatena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO 1)copper(II)]-μ-1,3-di-4-pyridylpropane-κ2 N:N′]
In the title compound, [Cu(C(8)H(4)NO(6))(2)(C(13)H(14)N(2))](n), the square-planar coordinated Cu(II) ion lies on an inversion centre and is coordinated by two protonated 5-nitro-isophthalate ligands. The Cu(II) ions are linked into a one-dimensional coordination polymer by tethering 1,3-di-4-pyridylpropane ligands, whose central methyl-ene C atoms are situated on twofold rotation axes. The ch...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008